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Beilstein J. Org. Chem. 2013, 9, 1170–1178, doi:10.3762/bjoc.9.131
Graphical Abstract
Figure 1: An aza-[3 + 3] annulation.
Scheme 1: Aza-[3 + 3] annulations with enones.
Figure 2: Possible natural-product targets.
Scheme 2: Synthesis of the annulation precursor enone 10.
Scheme 3: Propyleine-isopropeleine interconversion.
Figure 3: Relative stabilities of propyleine and isopropyleine.
Scheme 4: Retrosynthesis of propyleine (12).
Scheme 5: Synthesis of allyl alcohol 25.